USGS Issues Report On Long-Term Study Of VOCs In Nation's Groundwater, Drinking Water

A long-term investigation by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS) found volatile organic compounds (VOCs) in aquifers across the nation and not limited to just a few specific aquifers or regions.

USGS released a report on April 28 describing the occurrence of VOCs in groundwater and drinking-water supply wells across the nation. Despite the nationwide occurrence, VOCs were not detected in most of the sampled wells (about 80 percent had no detections above a threshold of 0.2 part per billion). VOCs were detected in some domestic and public-supply wells, but seldom at concentrations greater than EPA regulatory or USGS health-based guidelines, USGS officials said.

VOCs are produced in large volumes and are associated with a myriad of products, such as plastics, adhesives, paints, gasoline, fumigants, refrigerants, and dry-cleaning fluids.

Dr. Robert Hirsch, associate director for water of USGS, said, "VOCs are an important group of environmental contaminants to monitor and manage in groundwater because of their widespread and long-term use. Once released, VOCs tend to persist in the environment and migrate in groundwater, potentially to drinking-water supply wells. Some VOCs are of concern because of their potential carcinogenicity or other health effects, and because they can change the taste and odor of drinking water."

Hirsch also commented that "the USGS assessment provides the most comprehensive national-scale analysis to date of VOC occurrence in aquifers used as an important supply of drinking water."

The NAWQA VOC team has compiled a table that summarizes health effects of VOCs (http://water.usgs.gov/nawqa/vocs/national_assessment/aboutvocs). The compilation provides existing cancer classifications of many VOCs and summarizes the most recent VOC health-effects information published by EPA or the Agency for Toxic Substances and Disease Registry (ATSDR). EPA's Office of Water has developed technical fact sheets on VOCs (see http://www.epa.gov/safewater/dwh/t-voc.html). For regulated VOCs (those with Maximum Contaminant Levels -- or MCLs), EPA summarizes the potential health effects from ingestion of water at http://www.epa.gov/safewater/mcl.html. For most regulated compounds, this Web site links to consumer fact sheets that include information on why the compound is regulated, health effects information, how much of the chemical is produced, and what happens when the chemical is released into the environment. MCLs are the highest level of a contaminant that EPA allows in drinking water. MCLs ensure that drinking water does not pose either a short-term or long-term health risk.

The USGS report is based on analysis of groundwater samples from nearly 3,500 wells which are distributed randomly across broad regions and represent 98 aquifer studies across the nation -- from Florida to the Pacific Northwest, plus a regional study in the High Plains aquifer system. Most of the wells were sampled between 1985 and 2002. The study characterized large-scale resource occurrence of VOCs, and was not designed to evaluate localized VOC contamination of ground water, such as at landfills and leaking underground storage tanks. The report also presents a USGS analysis focused only on drinking-water supply wells, including more than 2,400 domestic and nearly 1,100 public wells.

Although the USGS study did not analyze drinking water after treatment, the results from drinking-water supply wells were compared to federal drinking-water standards and other human-health based benchmarks as an initial screening-level assessment.

According to senior author John Zogorski, "VOCs were detected in drinking-water supply wells -- specifically, in 14 percent of domestic wells and 26 percent of public wells, but only a small number of samples (less than 2 percent) had VOC concentrations that were greater than federal drinking-water standards. Concentrations greater than standards were accounted for by eight compounds, in large part by the solvents perchloroethene (PCE) and trichloroethene (TCE), and the agricultural fumigant dibromochloropropane (DBCP)."

Zogorski also explained that "VOCs were detected more frequently in public wells than in domestic wells. It is likely that the higher rate of detection of VOCs in public wells is a result of their larger withdrawal rates and their proximity to developed areas."

USGS findings suggest strong relations between VOCs in groundwater and percentage of urban land use within a half-kilometer radius of sampled wells. Zogorski added that "It is likely that urban areas have more sources of VOCs compared to other land-use settings. Source-water protection programs are critical for the effective management of VOC contamination, particularly for urban wells."

The report provides a detailed examination of which VOC compounds occur most frequently in ground water and general patterns and associations explaining where they may be found. VOCs were detected in 90 of 98 aquifer studies completed across the Nation. In general, detections of most VOC compounds were distributed across the Nation; a few VOCs, such as the gasoline oxygenate methyl tertiary-butyl ether (MTBE) and soil fumigants, were found in a few distinct regions.

Many of the aquifer samples had low concentrations of VOCs -- defined in the report as less than one part per billion. The prevalence of VOCs at low concentrations indicates the need for ground-water managers and policy makers to continue to manage and monitor the occurrence of these contaminants over the long term.

Each VOC has a unique pattern of occurrence depending on many factors related to its sources and to its persistence and transport in aquifers. The most frequently detected VOCs were chloroform, the solvents PCE and TCE, and MTBE. Thirteen VOCs were not detected at all.

An important source of chloroform appears to be related to the recycling of treated water that had been chlorinated or perhaps water exposed to household products that contain chlorine, such as bleach. Artificial recharge of water and wastewater containing chloroform, most likely resulting from water chlorination, is an increasingly common practice, particularly in the western area of the country.

MTBE is an oxygenate added to gasoline to improve combustion and reduce air pollution. MTBE has been intensively used in reformulated gasoline for only about 10 years, but its relatively high mobility and persistence has allowed it to reach groundwater, particularly in areas of high use in New England and Mid-Atlantic states. In 2005, federal legislation eliminated the oxygen requirement in gasoline, which is expected to decrease the use of MTBE in gasoline in the future.

PCE and TCE are organic compounds containing chlorine and are most often used as solvents in a variety of industrial, commercial, and domestic applications. For example, PCE is used as a dry cleaning solvent by most commercial dry cleaners. Production of PCE and TCE has been declining as early as the 1970s; monitoring over the long-term will help to track any changes in their concentrations in groundwater.

The report, "Volatile Organic Compounds in the NationĀ“s Ground Water and Drinking-Water Supply Wells," Circular 1292, is available at http://water.usgs.gov/nawqa/vocs/national_assessment.

This article originally appeared in the 05/01/2006 issue of Environmental Protection.

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